I downloaded the 2020 2500 manual and can verify that it is as Sdoctor86 posted. There is no longer a mention of 89 octane. Here is the full passage on octane cut and pasted from the 2020 manual:
FUEL REQUIREMENTS — GAS ENGINE
6.4L ENGINE
Do not use E-85 flex fuel or ethanol blends
greater than 15% in this engine.
This engine is designed to meet all
emissions regulations and provide
satisfactory fuel economy and
performance when using high quality
unleaded gasoline having a posted octane
number range of 87 as specified by the
(R+M)/2 method.
While operating on gasoline with an octane
number of 87, hearing a light knocking sound
from the engine is not a cause for concern.
However, if the engine is heard making a heavy
knocking sound, see dealer immediately. Use of
gasoline with an octane number lower than 87
can cause engine failure and may void or not be
covered by the New Vehicle Limited Warranty.
Poor quality gasoline can cause problems such
as hard starting, stalling, and hesitations. If you
experience these symptoms, try another brand
of gasoline before considering service for the
vehicle
FUEL REQUIREMENTS — GAS ENGINE
6.4L ENGINE
Do not use E-85 flex fuel or ethanol blends
greater than 15% in this engine.
This engine is designed to meet all
emissions regulations and provide
satisfactory fuel economy and
performance when using high quality
unleaded gasoline having a posted octane
number range of 87 as specified by the
(R+M)/2 method.
While operating on gasoline with an octane
number of 87, hearing a light knocking sound
from the engine is not a cause for concern.
However, if the engine is heard making a heavy
knocking sound, see dealer immediately. Use of
gasoline with an octane number lower than 87
can cause engine failure and may void or not be
covered by the New Vehicle Limited Warranty.
Poor quality gasoline can cause problems such
as hard starting, stalling, and hesitations. If you
experience these symptoms, try another brand
of gasoline before considering service for the
vehicle