You don’t need AlfaOBD to change the TPMS sensor thresholds. That is done with WiTech2 and a J2534 tool. It’s just a dropdown in the vehicle settings within WiTech2. If you have a working J2534 tool, it’s pretty simple to change that. The tool is quite expensive (several hundred dollars and up to $1,850) if you don’t have it for other reasons.
If you don’t have a tool, I would go to the dealer and have them do it. WiTech2 is the tool they use. It would take all of 5 minutes.
I’m in SoCal and may be able to help if you’re nearby. I have mine set at 42psi (45 isn’t an option) in my ‘26 Power Wagon.